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Synthetic Exploration of Bis(phenolate) Aza-BODIPYs and Heavier Group 13 Chelates


Journal article


Aiden M Lane, Ny T. C. Luong, Jordan C. Kelly, M. Neal, Jeremiah Jamrom, A. Bloomfield, P. Lummis, Thomas D. Montgomery, Daniel T Chase
Molecules, 2022

Semantic Scholar DOI PubMedCentral PubMed
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APA   Click to copy
Lane, A. M., Luong, N. T. C., Kelly, J. C., Neal, M., Jamrom, J., Bloomfield, A., … Chase, D. T. (2022). Synthetic Exploration of Bis(phenolate) Aza-BODIPYs and Heavier Group 13 Chelates. Molecules.


Chicago/Turabian   Click to copy
Lane, Aiden M, Ny T. C. Luong, Jordan C. Kelly, M. Neal, Jeremiah Jamrom, A. Bloomfield, P. Lummis, Thomas D. Montgomery, and Daniel T Chase. “Synthetic Exploration of Bis(Phenolate) Aza-BODIPYs and Heavier Group 13 Chelates.” Molecules (2022).


MLA   Click to copy
Lane, Aiden M., et al. “Synthetic Exploration of Bis(Phenolate) Aza-BODIPYs and Heavier Group 13 Chelates.” Molecules, 2022.


BibTeX   Click to copy

@article{aiden2022a,
  title = {Synthetic Exploration of Bis(phenolate) Aza-BODIPYs and Heavier Group 13 Chelates},
  year = {2022},
  journal = {Molecules},
  author = {Lane, Aiden M and Luong, Ny T. C. and Kelly, Jordan C. and Neal, M. and Jamrom, Jeremiah and Bloomfield, A. and Lummis, P. and Montgomery, Thomas D. and Chase, Daniel T}
}

Abstract

A series of boron, aluminum, gallium, and indium chelates containing the underexplored bis(phenolate) aza-dipyrromethene (aza-DIPY) core were prepared. These compounds were found to possess near-infrared absorption and emission profiles in the 710 to 770 nm domain and exhibit quantum yield values up to 14%. X-ray diffraction analysis revealed that heavier group 13 bis(phenolate) aza-DIPY chelates possessed octahedral geometries with either THF or pyridine groups occupying the axial positions as opposed to the tetrahedral geometry of the boron chelate.


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